The affinity of molten aluminum for picking up hydrogen is an insidious threat to production—it takes it up from wet raw materials, moist air, or contaminated lubricants and releases it in the form of bubbles when it solidifies. The bubbles create porosity, blisters, and reduced mechanical properties. It is not a question of option for manufacturers ranging from the automotive to aerospace industry. But how do manufacturers degas aluminum? The solution is found in a blend of effective techniques and accurate equipment, aluminum degassing machines being the foundation of contemporary purification.
Before exploring the "how," let's grasp the stakes. Molten aluminum is 50 times more prone to embrittlement than solid aluminum. When metals cool, hydrogen solubility drops dramatically, and dissolved gas produces defects: pinholes in foil, cracks in engine blocks, or structural weaknesses in aircraft. Trace amounts (greater than 0.15 cm³/100g) can reduce tensile strength by 30% and contribute 15–20% to annual scrap. Degassing isn't just a process step but a required quality control procedure.
For small-scale foundries, chemical methods are typically the method of choice. They use reactive fluxes to bond hydrogen into compounds that may be removed, and the process works in the following manner:
Operators submerge chlorine-releasing tablets (hexachloroethane, for instance) or flux granules into molten aluminum in a preheated perforated bell. High-temperature decomposed fluxes evolve gases such as aluminum chloride. The formed bubbles have extremely low hydrogen partial pressure, and the dissolved hydrogen is drawn into them by diffusion. They carry hydrogen and non-metallic inclusions upwards on their ascent, from which they are skimmed off as slag.
Though cheap and simple to apply, chemical degassing has drawbacks: toxic chlorine vapors (which demand severe ventilation), flux residues can pollute high-purity alloys, and its highest efficiency is 40%—not high enough for critical applications. Nowadays, it is mainly reserved for small lots or as preliminary treatment for mechanical refining.
In industrial manufacturing, inert gas degassing is the norm—and equipment for aluminum degassing ensures its success. It makes use of partial pressure difference phenomenon: inert gas bubbles (nitrogen or argon) are "sponges," absorbing hydrogen from molten metal (where it is found) into the bubbles (where it is not).
The key to this process is creating extremely small, evenly sized bubbles—and this is exactly what aluminum degassing machines excel at. Here is a step-by-step breakdown of how it's done:
More sophisticated aluminum degassing technologies now include flux injection, allowing for simultaneous degassing and deslagging. For instance, Pyrotek's SNIF™ process employs a proprietary rotating nozzle to inject gas in a non-turbulent manner, reducing half of dross formation and attaining a hydrogen removal efficiency of 60–80%.
When very low hydrogen content (≤0.05 cm³/100g) is required—like in aerospace alloys or capacitor foil—vacuum degassing is used by producers. It is achieved by subjecting molten aluminum to a sealed, low-pressure container: reduced pressure reduces solubility for hydrogen, pushing the gas out as bubbles that float up and vent.
Even though extremely effective, vacuum degassing is capital and energy expensive. In order to save time and cost, it is usually preceded by pre-treatment on an aluminum degassing machine that removes the bulk of the hydrogen before the vacuum step.
Success with any process depends on the control of key factors—most of which relate to aluminum degassing machines:
The best approach is a function of scale of production and quality requirements:
Aluminum degassing began as a rough chemical process and is now advanced engineering—and equipment for aluminum degassing is the pinnacle of it. By converting inert gas to an extremely precise purification tool, such equipment enables uniform, efficient hydrogen removal less expensively and with fewer defectives. Used with fluxes for limited-production runs or integrated into continuous aerospace manufacture, they yield molten aluminum of higher quality.
For manufacturers, the message is clear: find the degassing process that works best for you, but do not underestimate the aluminum degassing machine. It is not just machinery—it is the difference between making scrap and making a working product.
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